I think "tomorrow" is related to names of days of the week (Monday, Tuesday, etc.), and a calendar. My parents keep a (paper) calendar in the kitchen, I can see the days being crossed off one by one, so "today" moves from the beginning to the end of the month.
The (names of) the days of the week are worth knowing because of the weekly schedule: e.g. work on Monday, house-cleaning on Tuesday, playgroup on Wednesday, shopping on Thursday, etc. If you know that today is Wednesday then you can say that Tuesday is "yesterday". If you're not sure that "yesterday" is being used correctly, you can ask "do you mean Tuesday?" and point to the calendar.
Another useful time-keeping device is an analog kitchen clock with a sweeping second hand. You can see how the time changes from 1 to 2 to 3 and so on, and see that if it's 2 now then it used to be 1 and is going to be 3.
It's also useful to know the names of the parts of the day: dawn, breakfast-time, morning, lunch-time, afternoon, supper-time, evening, night-time. Correlate that with activities (e.g. "have a bath after supper and before bed").
Lastly, we have grammar. Statements like "I went tomorrow" and "I will go yesterday" are ungrammatical: they sound wrong to an adult. I think that (young) children are wired to learn or "soak up" grammar by hearing it spoken. If you hear "I went tomorrow" and you know (from the context) what the correct statement is, you can teach it just by repeating the correct statement with a tiny emphasis (e.g. say "I went yesterday" or "I will go tomorrow") without explaining it in depth each time.